| dc.contributor.author |
Singh, Suraj |
|
| dc.contributor.author |
Kumar, Rohtash |
|
| dc.contributor.author |
Dubey, Navneet Nandgopal |
|
| dc.contributor.author |
Appayee, Chandrakumar |
|
| dc.coverage.spatial |
United Kingdom |
|
| dc.date.accessioned |
2024-08-02T14:02:37Z |
|
| dc.date.available |
2024-08-02T14:02:37Z |
|
| dc.date.issued |
2024-07 |
|
| dc.identifier.citation |
Singh, Suraj; Kumar, Rohtash; Dubey, Navneet Nandgopal and Appayee, Chandrakumar, "Synthesis and application of chiral cis-2,5-disubstituted pyrrolidine organocatalysts", Chemical Communications, DOI: 10.1039/D4CC03132F, Jul. 2024. |
|
| dc.identifier.issn |
1359-7345 |
|
| dc.identifier.issn |
1364-548X |
|
| dc.identifier.uri |
https://doi.org/10.1039/D4CC03132F |
|
| dc.identifier.uri |
https://repository.iitgn.ac.in/handle/123456789/10288 |
|
| dc.description.abstract |
The first synthesis of chiral cis-2,5-disubstituted pyrrolidine organocatalysts is described. Their application for the enantioselective Michael addition of nitromethane to α,β-unsaturated aldehydes with excellent yield (up to 91%) and enantioselectivity (up to >99% ee) is demonstrated. Another catalytic application for the reaction of 2,4-hexadienal with nitrostyrene is also showcased. |
|
| dc.description.statementofresponsibility |
by Suraj Singh, Rohtash Kumar, Navneet Nandgopal Dubey and Chandrakumar Appayee |
|
| dc.language.iso |
en_US |
|
| dc.publisher |
Royal Society of Chemistry |
|
| dc.title |
Synthesis and application of chiral cis-2,5-disubstituted pyrrolidine organocatalysts |
|
| dc.type |
Article |
|
| dc.relation.journal |
Chemical Communications |
|