A nanotube-supported dicopper complex enhances Pt-free molecular H2/Air fuel cells

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dc.contributor.author Gentil, Sol�ne
dc.contributor.author Molloy, Jennifer K.
dc.contributor.author Carri�re, Marie
dc.contributor.author Hobballah, Ahmad
dc.contributor.author Dutta, Arnab
dc.contributor.author Cosnier, Serge
dc.contributor.author Shaw, Wendy J.
dc.contributor.author Gellon, Gis�le
dc.contributor.author Belle, Catherine
dc.contributor.author Artero, Vincent
dc.contributor.author Thomas, Fabrice
dc.contributor.author Le Goff, Alan
dc.date.accessioned 2019-09-12T05:23:36Z
dc.date.available 2019-09-12T05:23:36Z
dc.date.issued 2019-08
dc.identifier.citation Dutta, Arnab et al., �A nanotube-supported dicopper complex enhances Pt-free molecular H2/Air fuel cells�, Joule, DOI: 10.1016/j.joule.2019.07.001, vol. 3, no. 8, pp. 2020-2029, Aug. 2019. en_US
dc.identifier.issn 2542-4351
dc.identifier.uri https://doi.org/10.1016/j.joule.2019.07.001
dc.identifier.uri https://repository.iitgn.ac.in/handle/123456789/4816
dc.description.abstract A dinuclear copper complex mimicking the active site of copper oxidase was designed and ?-stacked on a carbon nanotube (CNT) electrode thanks to pendent pyrene groups. The high oxygen reduction reaction activity of such CNT-supported dicopper complexes in pH 4 electrolyte allowed the construction of a Pt-free hydrogen/air fuel cell using bioinspired nickel bis-diphosphine complexes immobilized onto CNT at the anode, with an order-of-magnitude improvement of the performance compared to previous literature data. This bioinspired nickel- and copper-based H2/air fuel cell reaches a maximum power density of 0.15 mW cm?2 at 0.25 V and pH 4.
dc.description.statementofresponsibility by by Arnab Dutta et al.
dc.format.extent vol. 3, no. 8, pp. 2020-2029
dc.language.iso en_US en_US
dc.publisher Elsevier en_US
dc.title A nanotube-supported dicopper complex enhances Pt-free molecular H2/Air fuel cells en_US
dc.type Article en_US
dc.relation.journal Joule


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