| dc.contributor.author |
Pandey, Vijayalakshmi |
|
| dc.contributor.author |
Jain, Drishti |
|
| dc.contributor.author |
Pareekh, Nitesh |
|
| dc.contributor.author |
Gupta, Iti, |
|
| dc.date.accessioned |
2019-12-18T12:44:34Z |
|
| dc.date.available |
2019-12-18T12:44:34Z |
|
| dc.date.issued |
2019-12 |
|
| dc.identifier.citation |
Pandey, Vijayalakshmi; Jain, Drishti; Pareekh, Nitesh; and Gupta, Iti, "Pd(II) porphyrins: synthesis, singlet oxygen generation and photoassisted oxidation of aldehydes to carboxilic acids", Inorganica Chimica Acta, DOI: 10.1016/j.ica.2019.119339, Dec. 2019. |
en_US |
| dc.identifier.issn |
0020-1693 |
|
| dc.identifier.uri |
https://doi.org/10.1016/j.ica.2019.119339 |
|
| dc.identifier.uri |
https://repository.iitgn.ac.in/handle/123456789/5031 |
|
| dc.description.abstract |
The synthesis and spectral studies of A3B and A2B2 type porphyrins and their Pd(II) complexes are reported. The meso-positions on porphyrin macrocycle are substituted with pentafluorophenyl and N-butylcarbazole or triphenylamine groups. Pd(II) porphyrins displayed decent phosphorescence ?670 nm and are able to produce singlet oxygen by type II pathway, after photoirradiation. The calculated singlet oxygen quantum yields for Pd(II) porphyrins are (??= 30% to 63%). The catalytic application of Pd(II) porphyrins towards photoassisted aerobic oxidation of aromatic aldehydes to carboxylic acids is demonstrated. |
|
| dc.description.statementofresponsibility |
by Vijayalakshmi Pandey, Drishti Jain, NiteshPareekh and Iti Gupta |
|
| dc.language.iso |
en_US |
en_US |
| dc.publisher |
Elsevier |
en_US |
| dc.subject |
Singlet oxygen |
en_US |
| dc.subject |
Photosensitizer |
en_US |
| dc.subject |
Palladium porphyrins |
en_US |
| dc.subject |
Catalyst |
en_US |
| dc.subject |
Oxidation |
en_US |
| dc.title |
Pd(II) porphyrins: synthesis, singlet oxygen generation and photoassisted oxidation of aldehydes to carboxilic acids |
en_US |
| dc.type |
Article |
en_US |
| dc.relation.journal |
Inorganica Chimica Acta |
|