| dc.contributor.author |
Janaagal, Anu |
|
| dc.contributor.author |
Pandey, Vijayalakshmi |
|
| dc.contributor.author |
Sabharwal, Sudhir |
|
| dc.contributor.author |
Gupta, Iti |
|
| dc.coverage.spatial |
United States of America |
|
| dc.date.accessioned |
2021-05-20T05:13:45Z |
|
| dc.date.available |
2021-05-20T05:13:45Z |
|
| dc.date.issued |
2021-04 |
|
| dc.identifier.citation |
Janaagal, Anu; Pandey, Vijayalakshmi; Sabharwal, Sudhir and Gupta, Iti, “meso-Carbazole substituted palladium porphyrins: efficient catalysts for visible light induced oxidation of aldehydes”, Journal of Porphyrins and Phthalocyanines, DOI: 10.1142/S1088424621500486, vol. 25, no.5-6, pp. 571-581, May 2021. |
en_US |
| dc.identifier.issn |
1088-4246 |
|
| dc.identifier.issn |
1099-1409 |
|
| dc.identifier.uri |
https://doi.org/10.1142/S1088424621500486 |
|
| dc.identifier.uri |
https://repository.iitgn.ac.in/handle/123456789/6510 |
|
| dc.description.abstract |
The A3B and A2B2 type porphyrins having N-butylcarbazole and p-cyanophenyl groups are synthesized and characterized. Their palladium complexes have also been prepared and utilized as catalysts for the photo-oxidation reactions of aromatic aldehydes in good yields. Pd(II)porphyrins displayed decent phosphorescence at ~670 nm and were able to generate singlet oxygen upon light irradiation. The calculated singlet oxygen quantum yields for Pd(II)porphyrins were between 57% and 73%. The photo-catalytic application of Pd(II)porphyrins for aerobic oxidation of aromatic aldehydes is demonstrated. |
|
| dc.description.statementofresponsibility |
by Anu Janaagal, Vijayalakshmi Pandey, Sudhir Sabharwal and Iti Gupta |
|
| dc.format.extent |
vol. 25, no. 5-6, pp. 571-581 |
|
| dc.language.iso |
en_US |
en_US |
| dc.publisher |
Wiley |
en_US |
| dc.subject |
singlet oxygen |
en_US |
| dc.subject |
photo-catalysis |
en_US |
| dc.subject |
palladium-porphyrins |
en_US |
| dc.subject |
oxidation |
en_US |
| dc.subject |
DFT studies |
en_US |
| dc.title |
meso-Carbazole substituted palladium porphyrins: efficient catalysts for visible light induced oxidation of aldehydes |
en_US |
| dc.type |
Article |
en_US |
| dc.relation.journal |
Journal of Porphyrins and Phthalocyanines |
|