Abstract:
This work is focused on the design and synthesis of homoleptic & heteroleptic dipyrrinato complexes with palladium at the centre. The C-5 position of dipyrrin ligand was substituted with pentaflourophenyl/naphthalene/tetraphenylethylene moieties. Scanning electron microscopy (SEM) measurement revealed the formation of aggregates in the binary solvents for homoleptic Pd(II) complexes. These complexes showed enhanced emission with noticeable red shifts (20-30 nm) in the aggregated stage, suggesting the formation of J-aggregates in THF/water mixture. All the Pd(II)dipyrrinato complexes exhibited strong absorption in the range of 440-560 nm; the DFT optimized geometries also showed absorption transitions similar to the experimentally observed values. Pd3 complex with pentafluorphenyl groups was able to generate efficient singlet oxygen in polar solvents. Also, Pd3 was used to catalyse the photo-oxidation of aromatic aldehydes in good yields (51-93%) in the presence of white LED.