Hydrodynamics of a confined active Belousov-Zhabotinsky droplet

Abstract

Self-sustained locomotion of synthetic droplet swimmers has been of great interest due to their ability to mimic the behavior of biological swimmers. Here we harness the Belousov-Zhabotinsky (BZ) reaction to induce Marangoni stresses on the fluid-droplet interface and elucidate the spontaneous locomotion of active BZ droplets in a confined two-dimensional channel. Our approach employs the lattice Boltzmann method to simulate a coupled system of multiphase hydrodynamics and BZ-reaction kinetics. Our investigation reveals the mechanism underlying the propulsion of active BZ droplets, in terms of convective and diffusive fluxes and deformation of the droplets. Furthermore, we demonstrate that by manipulating the degree of confinement, strength, and nature of coupling between surface tension and active species' concentration, the motion of the BZ droplet can be directed. In addition, we are able to capture two different kinds of droplet behaviors, namely, sustained and stationary, and establish conditions for the sustained long-time motion. We envisage that our findings can be used not only to understand the mechanics of biological swimmers but also to design reaction-driven self-propelled systems for a variety of biomimetic applications.